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Lecture Notes
Alan D. Earhart
= Southeast Community College • Lincoln, NE
Chapter 1 <= /div>
Chemistry: Matter and Measurement
John E. McMurry • Robert C. Fay=
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Fif= th Edition
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= Copyright © 2008 Pearson Prentice Hall, Inc.
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= Chapter 1: Chemistry: Matter and Measurement
= 9/23/2008
= Copyright © 2008 Pearson Prentice Hall, Inc.
= ‹#›
------=_NextPart_01C91D68.307CCF60 Content-Location: file:///C:/A7293656/c1210L16_files/pres.xml Content-Transfer-Encoding: quoted-printable Content-Type: text/xml; charset="utf-8" ------=_NextPart_01C91D68.307CCF60 Content-Location: file:///C:/A7293656/c1210L16_files/slide0124.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
3D"04_P25"
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Aci= d/Base and Redox Reactions=
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 1/2
------=_NextPart_01C91D68.307CCF60 Content-Location: file:///C:/A7293656/c1210L16_files/slide0106.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 4/3
Acids, Bases, and Neutralization Reactions
H3O1+(aq) + Cl1-= (aq)
HCl(aq) + H2O(aq)
Acid (Arrhenius):= A substance that dissociates in water to produce hydrogen ions, H1+:
H1+(aq) + A1-(aq)<= /div>
HA(aq)
In water, acids produce hydronium ions, H3<= /span>O1+= :
H1+(aq) + Cl1-= (aq)
HCl(aq)
“= ;HA” is a generic chemical formula for an acid.
Hydrog= en ions do not exist in water. They are attached to one or more water molecules (often in clusters).
For convenience, we’ll write it as hydrogen ion instead of hydron= ium ion until a later chapter when a deeper look at acids and bases is undertaken.
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Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhZQEcAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALKAACwAb AAYAgAAAAAAAAAIUhI+poe0Z4om02ouz1q9P6oUMUgAAOw== ------=_NextPart_01C91D68.307CCF60 Content-Location: file:///C:/A7293656/c1210L16_files/slide0106_image006.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlh/ABEAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALEsACgAb AC8AgAAAAAAAAAJFhI+poe0Z2Jswnoiz3hyw74Xg6GUUhZ2npLbuC8fyTNf2jef6zvf+DwwKh8Si 8YhMKpeXnOWWMnCm1BTpKhKZaNEay1AAADs= ------=_NextPart_01C91D68.307CCF60 Content-Location: file:///C:/A7293656/c1210L16_files/slide0107.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 4/4
Acids, Bases, and Neutralization Reactions
Ammonia, commonly called “ammonium hydroxide” is a base:
M1+(aq) + OH1-= (aq)
MOH(aq)
Na1+(aq) + OH1-= (aq)
NaOH(aq)
NH41+(aq) + OH1-= (aq)
NH3(aq) + H2O(aq)<= /div>
Base (Arrhenius):= A substance that dissociates in water to produce hydroxide ions, OH1-:
“= ;M” is shorthand for a metal cation.
ItR= 17;s really not proper to call “aqueous ammonia” “ammonium hydroxide” even though it’s still commonly labeled as such (ordering chemicals, etc.).
------=_NextPart_01C91D68.307CCF60 Content-Location: file:///C:/A7293656/c1210L16_files/slide0107_image007.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhIwFEAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALF8ACgAb AC8AgAAAAAAAAAJFhI+poe0Z2Jswnoiz3hyw74Xg6GUUhZ2npLbuC8fyTNf2jef6zvf+DwwKh8Si 8YhMKpeXnOWWMnCm1BTpKhKZaNEay1AAADs= ------=_NextPart_01C91D68.307CCF60 Content-Location: file:///C:/A7293656/c1210L16_files/slide0107_image008.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhcQEcAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALKMACgAb AAcAgAAAAAAAAAIdhI+poe0ZGGIU1Gtz3Hb7D4bYqJXfgx5RyhrSUQAAOw== ------=_NextPart_01C91D68.307CCF60 Content-Location: file:///C:/A7293656/c1210L16_files/slide0108.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 4/5
Acids, Bases, and Neutralization Reactions
Weak acids and weak bases are weak electrolytes.
Strong acids and strong bases are strong electrolytes.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 4/6
Acids, Bases, and Neutralization Reactions
MA   +   H2<= /span>O
HA   +   MOH
These acid-base neutralization reactions are double-replacement reactions just like the precipitation reactions:
or
MA   +   = HOH
HA   +   M= OH
Water
Acid
Base
Salt
Recall= the original definition of an acid-base neutralization written earlier.
While = it looks goofy to write water as HOH, it can help students remember where the pieces came from: H (acid) and OH (base). It’s also easier to balance.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 4/7
Write the chemical formul= as of the products (use proper ionic rules for the salt).
1.
Acids, Bases, and Neutralization Reactions
Write the molecular, ioni= c, and net ionic equations for the reaction of aqueous HBr and aque= ous Ba(OH)2.
H2O
HBr(aq)
+
Ba(OH)2(aq)
+
BaBr2
Salt
Acid
Base
Water
The or= der the products are written in is irrelevant.
The pr= oducts will be water and a salt.
The sa= lt is written using the rules for naming ionic compounds as previously used.
------=_NextPart_01C91D68.307CCF60 Content-Location: file:///C:/A7293656/c1210L16_files/slide0110_image013.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhHgAKAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAEAAgAb AAYAgAAAAAAAAAIXhI+py30BEZy0WgtC3rrzXzliNo2ihhQAOx== ------=_NextPart_01C91D68.307CCF60 Content-Location: file:///C:/A7293656/c1210L16_files/slide0111.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 4/8
Molecular Equation: Balance the equation and predict the solubility of the salt in the products.
2.
Acids, Bases, and Neutralization Reactions
Write the molecular, ioni= c, and net ionic equations for the reaction of aqueous HBr and aque= ous Ba(OH)2.
2H2O(l) + BaBr2<= /span>(aq)
2HBr(aq) + Ba(OH)2(aq)
Use the solubility rules.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 4/9
Ionic Equation: Dissociate a strong acid and the soluble ionic compounds.<= /span>
3.
Acids, Bases, and Neutralization Reactions
Write the molecular, ioni= c, and net ionic equations for the reaction of aqueous HBr and aque= ous Ba(OH)2.
2H2O(l) + Ba2+(aq) + 2Br1-(aq)
2H1+(aq) + 2Br1-= (aq) + Ba2+(aq) + 2OH1-(aq)
BaBr2(aq)
2HBr(aq)
Ba(OH)2(aq)
HBr is= one of the 6 strong acids.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/10
2H2O(l) + Ba2+(aq) + 2Br1-(aq)
Acids, Bases, and Neutralization Reactions
Write the molecular, ioni= c, and net ionic equations for the reaction of aqueous HBr and aque= ous Ba(OH)2.
Net Ionic Equation: Eliminate the spectator ions from the ionic equation.
4.
2H1+(aq) + 2Br1-= (aq) + Ba2+(aq) + 2OH1-(aq)
or
H2O(l)
H1+(aq) + OH1-= (aq)
2H2O(l)
2H1+(aq) + 2OH1-= (aq)
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/11
Acids, Bases, and Neutralization Reactions
Write the molecular, ioni= c, and net ionic equations for the reaction of aqueous NaOH and aqu= eous HF.
Write the chemical formul= as of the products (use proper ionic rules for the salt).
1.
Salt
Acid
Base
Water
H2O
HF(aq) + NaOH(aq)
+
NaF
------=_NextPart_01C91D68.307CCF60 Content-Location: file:///C:/A7293656/c1210L16_files/slide0114_image025.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhHgAKAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAEAAgAb AAYAgAAAAAAAAAIYhI+py30BH5y02moC0Hz7DlLOuEXkqCEFADs= ------=_NextPart_01C91D68.307CCF60 Content-Location: file:///C:/A7293656/c1210L16_files/slide0115.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/12
Acids, Bases, and Neutralization Reactions
Write the molecular, ioni= c, and net ionic equations for the reaction of aqueous NaOH and aqu= eous HF.
Molecular Equation: Balance the equation and predict the solubility of the salt in the products.
2.
H2O(l) + NaF(aq)
HF(aq) + NaOH(aq)
Use the solubility rules.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/13
Acids, Bases, and Neutralization Reactions
Write the molecular, ioni= c, and net ionic equations for the reaction of aqueous NaOH and aqu= eous HF.
Ionic Equation: Dissociate a strong acid and the soluble ionic compounds.<= /span>
3.
H2O(l) + Na1+(aq) = + F1-= (aq)
HF(aq) + Na1+(aq) + OH= 1-= (aq)
NaF(aq)
NaOH(aq)
HF is = a weak acid. Since it dissociates only to a small degree in solution, it is not dissociated in the ionic equation.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/14
Acids, Bases, and Neutralization Reactions
Write the molecular, ioni= c, and net ionic equations for the reaction of aqueous NaOH and aqu= eous HF.
Net Ionic Equation: Eliminate the spectator ions from the ionic equation.
4.
H2O(l) + Na1+(aq) = + F1-= (aq)
HF(aq) + Na1+(aq) + OH= 1-= (aq)
H2O(l) + F1-(aq)<= /div>
HF(aq) + OH1-(aq)
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/15
Oxidation-Reduction (Redox)= Reactions
2Fe2O3(s)
4Fe(s) + 3O2(g)
Rusting of iron:
an oxidation of Fe
4Fe(s) + 3CO2(g)
2Fe2O3(s) + 3C(s)<= /div>
Manufacture of iron: a reduction of Fe
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3D"04_U06p117"
Aqueous
potassium
permanganate
Aqueou= s potassium permanganate, deep purple in color, is frequently used as an oxidizing agent, as described in the text.
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Content-Location: file:///C:/A7293656/c1210L16_files/slide0126.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
3D"04_U07p117"
Magnesium
metal
Magnes= ium metal burns in air to give MgO.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/18
Oxidation-Reduction (Redox)= Reactions
1.An atom in its elemental state has an oxidation number of 0.
Rules for Assigning Oxidation Numbers
Oxidation Number (Sta= te): A value which indicates whether an atom is neutral, electron-rich, or electron-poor.
Na
H2
Br2
S
Ne
Oxidation number 0
Page 118
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/19
Oxidation-Reduction (Redox)= Reactions
2.A monatomic ion has an oxidation number identical to its charge.
Na1+
+1
Ca2+
+2
Al3+
+3
Cl1-
-1
O2-
-2
This i= s why charges are supposed to be written as “1-”. The corresponding oxidati= on number is written “-1”.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/20
Oxidation-Reduction (Redox)= Reactions
<= span style=3D'mso-special-format:"numbullet9\,2";position:absolute;left:-5.88%'= >b)Oxygen usually has an oxidation number of -2.
H
O
1-
-2
+1
H
H
Ca
-1
-1
+2
= 3.An atom in a polyatomic ion or in a molecular compound usually has the = same oxidation number it would have if it were a monatomic ion. <= /span>
<= span style=3D'mso-special-format:"numbullet9\,1";position:absolute;left:-7.0%'>= a)Hydrogen can be either +1 or -1.
O
H
O
=
-1
+1
-1
H
H
O
+1
+1
-2
H
+1
H bond= ed to a nonmetal has an oxidation number of +1.
H bond= ed to a metal has an oxidation number of -1.
In per= oxides, O22-, oxygen has an oxidation number of -1.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/21
Oxidation-Reduction (Redox)= Reactions
H
Cl
+1
-1
<= span style=3D'mso-special-format:"numbullet9\,3";position:absolute;left:-5.52%'= >c)Halogens usually have an oxidation number of -1.
3.
Cl
Cl
O
+1
+1
-2
A majo= r exception is when the halogen is bonded to oxygen.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/22
Oxidation-Reduction (Redox)= Reactions
Cr2O7<= /span>2-=
-2
+1
x
4.The sum of the oxidation numbers is 0 for a neutral compound and is equal to the net charge for a polyatomic ion.
x =3D +6
2(x) + 7(-2) = =3D -2 (net charge)
H2SO3<= /span>
x
-2
x =3D +4
2(+1) + x + 3(= -2) =3D 0 (net charge)
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3D"04_U11p118"
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H15 – C4
•4.9 – 4.11, 4.= 27*, 4.57, 4.59, 4.63*, 4.65*, 4.101*
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= Chapter 1: Chemistry: Matter and Measurement
= 9/23/2008
Click to edit Master text styles
Second level
Third level
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= Copyright © 2008 Pearson Prentice Hall, Inc.
= ‹#›
1
Chapter 1: Chemistry: Matter and Measurement
9/23/2008
Copyright © 2008 Pearson Prentice Hall, Inc.
2
Chapter 4: Reactions in Aqueous Solution
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Copyright © 2008 Pearson Prentice Hall, Inc.
3
“HA” is a generic chemical formula for an acid.=
Hydrogen ions do not exist in water. They are attached to o= ne or more water molecules (often in clusters).
For convenience, we’ll write it as hydrogen ion instead of hydronium ion until a later chapter when a deeper look at acids and bases is underta= ken.
Chapter 4: Reactions in Aqueous Solution
9/23/2008
Copyright © 2008 Pearson Prentice Hall, Inc.
4
“M” is shorthand for a metal cation.
It’s really not proper to call “aqueous ammonia” “ammonium hydroxide” even though it’s sti= ll commonly labeled as such (ordering chemicals, etc.).
Chapter 4: Reactions in Aqueous Solution
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Copyright © 2008 Pearson Prentice Hall, Inc.
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Chapter 4: Reactions in Aqueous Solution
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Copyright © 2008 Pearson Prentice Hall, Inc.
6
Recall the original definition of an acid-base neutralizati= on written earlier.
While it looks goofy to write water as HOH, it can help stu= dents remember where the pieces came from: H (acid) and OH (base). It’s al= so easier to balance.
Chapter 4: Reactions in Aqueous Solution
9/23/2008
Copyright © 2008 Pearson Prentice Hall, Inc.
7
The order the products are written in is irrelevant.
The products will be water and a salt.
The salt is written using the rules for naming ionic compou= nds as previously used.
Chapter 4: Reactions in Aqueous Solution
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Chapter 4: Reactions in Aqueous Solution
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9
HBr is one of the 6 strong acids.
Chapter 4: Reactions in Aqueous Solution
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Chapter 4: Reactions in Aqueous Solution
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Chapter 4: Reactions in Aqueous Solution
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Copyright © 2008 Pearson Prentice Hall, Inc.
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Chapter 4: Reactions in Aqueous Solution
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Copyright © 2008 Pearson Prentice Hall, Inc.
13
HF is a weak acid. Since it dissociates only to a small deg= ree in solution, it is not dissociated in the ionic equation.
Chapter 4: Reactions in Aqueous Solution
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Chapter 4: Reactions in Aqueous Solution
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Aqueous potassium permanganate, deep purple in color, is frequently used as an oxidizing agent, as described in the t= ext.
17
Magnesium metal burns in air to give MgO.
Chapter 4: Reactions in Aqueous Solution
9/23/2008
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Chapter 4: Reactions in Aqueous Solution
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This is why charges are supposed to be written as “1-”. The corresponding oxidation number is written “-1”.
Chapter 4: Reactions in Aqueous Solution
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Copyright © 2008 Pearson Prentice Hall, Inc.
20
H bonded to a nonmetal has an oxidation number of +1. <= /div>
H bonded to a metal has an oxidation number of -1.
In peroxides, O22-, oxygen has an oxidation number of -1.
Chapter 4: Reactions in Aqueous Solution
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Copyright © 2008 Pearson Prentice Hall, Inc.
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A major exception is when the halogen is bonded to oxygen.<= /div>
Chapter 4: Reactions in Aqueous Solution
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hrefList("slide0126.htm",1,-1,1),new hrefList("slide01= 19.htm",1,-1,1),new hrefList("slide0120.htm",1,-1,1),new hrefList("slide012= 1.htm",1,-1,1),new hrefList("slide0122.htm",1,-1,1),new hrefList("slide0123= .htm",1,-1,1),new hrefList("slide0127.htm",1,-1,1),new hrefList("slide0128.= htm",1,-1,1),new hrefList("slide0129.htm",1,-1,1),new hrefList("slide0130.h= tm",1,-1,1),new hrefList("slide0131.htm",1,-1,1),new hrefList("slide0132.ht= m",1,-1,1),new hrefList("slide0133.htm",1,-1,1),new hrefList("slide0134.htm= ",1,-1,1),new hrefList("slide0135.htm",1,-1,1),new hrefList("slide0136.htm"= ,1,-1,1),new hrefList("slide0137.htm",1,-1,1),new hrefList("slide0138.htm",= 1,-1,1),new hrefList("slide0139.htm",1,-1,1),new hrefList("slide0140.htm",1= ,-1,1),new hrefList("slide0141.htm",1,-1,1),new hrefList("slide0142.htm",1,= -1,1),new hrefList("slide0143.htm",1,-1,1),new hrefList("slide0144.htm",1,-= 1,1),new hrefList("slide0145.htm",1,-1,1),new hrefList("slide0146.htm",1,-1= ,1),new hrefList("slide0147.htm",1,-1,1),new hrefList("slide0148.htm",1,-1,= 1),new hrefList("slide0149.htm",1,-1,1),new hrefList("slide0150.htm",1,-1,1= ),new hrefList("slide0151.htm",1,-1,1),new hrefList("slide0152.htm",1,-1,1)= ,new hrefList("slide0153.htm",1,-1,1),new hrefList("slide0154.htm",1,-1,1),= new hrefList("slide0155.htm",1,-1,1),new hrefList("slide0156.htm",1,-1,1),n= ew hrefList("slide0157.htm",1,-1,1),new hrefList("slide0158.htm",1,-1,1),ne= w hrefList("slide0159.htm",1,-1,1),new hrefList("slide0160.htm",1,-1,1),new= hrefList("slide0161.htm",1,-1,1),new hrefList("slide0162.htm",1,-1,1),new = hrefList("slide0163.htm",1,-1,1),new hrefList("slide0164.htm",1,-1,1),new h= refList("slide0165.htm",1,-1,1),new hrefList("slide0166.htm",1,-1,1),new hr= efList("slide0167.htm",1,-1,1),new hrefList("slide0168.htm",1,-1,1),new hre= fList("slide0169.htm",1,-1,1),new hrefList("slide0170.htm",1,-1,1),new href= List("slide0171.htm",1,-1,1),new hrefList("slide0172.htm",1,-1,1),new hrefL= ist("slide0173.htm",1,-1,1),new hrefList("slide0174.htm",1,-1,1),new hrefLi= st("slide0175.htm",1,-1,1),new hrefList("slide0176.htm",1,-1,1),new hrefLis= t("slide0177.htm",1,-1,1),new hrefList("slide0178.htm",1,-1,1),new hrefList= ("slide0179.htm",1,-1,1),new hrefList("slide0104.htm",1,-1,1)); function FullScrInit() { g_allowAdvOnClick =3D GetCurSld().mAdvOnClk document.body.style.backgroundColor=3D"black" document.oncontextmenu=3Dparent._CM; document.onkeydown =3D _KDH; document.ondragstart=3DCancel document.onselectstart=3DCancel self.focus() } function Redirect( frmId ) { var str=3Ddocument.location.hash,idx=3Dstr.indexOf('#'), sId=3DGetSldId() if(idx>=3D0) str=3Dstr.substr(1); if( window.name !=3D frmId && ( sId !=3D str) ) { obj =3D GetObj("Main-File") window.location.href=3Dobj.href+"#"+sId return 1 } return 0 } var MHTMLPrefix =3D CalculateMHTMLPrefix(); function CalculateMHTMLPrefix() { if ( document.location.protocol =3D=3D 'mhtml:') { href=3Dnew String(document.location.href) Start=3Dhref.indexOf('!')+1 End=3Dhref.lastIndexOf('/')+1 if (End < Start) return href.substring(0, Start) else return href.substring(0, End) } return ''; } function GetTags(base,tag) { if(g_supportsPPTHTML) return base.all.tags(tag); else return base.getElementsByTagName(tag); } function UpdNtsPane(){ if(frames["PPTNts"]) PPTNts.location.replace( MHTMLP= refix+GetHrefObj( gCurSld ).mNtsHref ) } function UpdNavPane( sldIndex ){ if(gNavLoaded) PPTNav.UpdNav() } function UpdOtNavPane(){ if(gOtlNavLoaded) PPTOtlNav.UpdOtlNav() } function UpdOtlPane(){ if(gOtlLoaded) PPTOtl.UpdOtl() } function SetHasNts( fVal ) { if( gHasNts !=3D fVal ) { gHasNts=3DfVal UpdNavPane() } } function ToggleOtlText() { gOtlTxtExp=3D!gOtlTxtExp UpdOtlPane() } function ClearMedia() { if (PPTSld.pptSound) PPTSld.pptSound.loop =3D 0; } function FullScreen() { if ( PPTSld.g_animUseRuntime ) PPTSld.document.body.pause(); ClearMedia(); var href =3D ( document.location.protocol =3D=3D 'mhtml:') ? FULLSCR_HREF = : FULLSCR_HREF+"#"+GetHrefObj(gCurSld).mSldHref; if(PPTNav.event.ctrlKey) { var w =3D (window.screen.availWidth * 1.0) / 2.0 var h =3D w * (PPTSld.g_origH * 1.0) / PPTSld.g_origW win =3D window.open( MHTMLPrefix+href,null,"toolbar=3D0,resizable=3D1,top= =3D0,left=3D0," + "width=3D"+ w + ",height=3D" + h ); if( win.document.body && PPTSld.g_animUseRuntime ) win.document.body.PPTSldFrameset=3Dwindow; } else { win =3D window.open( MHTMLPrefix+href,null,"fullscreen=3Dyes" ); if( win.document.body && PPTSld.g_animUseRuntime ) win.document.body.PPTSldFrameset=3Dwindow; } } function ToggleVNarration() { rObj=3DPPTSld.document.all("NSPlay") if( rObj && !PPTSld.g_animUseRuntime ) { if( (rObj.playState =3D=3D 1)||(rObj.playState =3D=3D 0) ) rObj.Play() else if( rObj.playState =3D=3D 2 ) rObj.Pause() else return; } else if( PPTSld.g_animUseRuntime ) { narObj =3D PPTSld.document.all("narrationID") if( narObj ) narObj.togglePause() } } function GetCurSldNum() { obj=3DGetHrefObj(gCurSld) if( obj.mOrigVis =3D=3D 1 ) return obj.mSldIdx else return gCurSld } function GetNumSlds() { if( GetHrefObj(gCurSld).mOrigVis =3D=3D 1 ) return GetSldList().mNumVisSlds; else return GetSldList().mList.length } function GetSldNum( href ) { for(ii=3D0; ii 1 ) PopSldList(); else if( !IsFramesMode() ) { if( gLoopCont ) GoToFirst() else EndShow() } } function GoToPrevSld() { ii=3DgCurSld-1 if( ii > 0 ) { obj=3DGetHrefObj(ii) while ( obj && ( obj.mVis =3D=3D 0 ) && ( ii>0 ) ) obj=3DGetHrefObj(--ii) if( ii =3D=3D 0 ) ii=3D1 GoToSldNum(ii) } } function GoToFirst(){ GoToSld( GetHrefObj(1).mSldHref ) } function GoToLast() { ii=3DGetSldList().mList.length if( ii !=3D gCurSld ) GoToSld( GetHrefObj(ii).mSldHref ) } function GoToSldNum( num ) { if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue obj =3D GetHrefObj( num ) obj.mVis=3D1 gPrevSld=3DgCurSld gCurSld =3D num; PPTSld.location.replace(MHTMLPrefix+obj.mSldHref) if( IsFramesMode() ) { UpdNavPane(); UpdOtlPane(); UpdNtsPane() } } function GoToSld( href ) { if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue GetHrefObj( GetSldNum(href) ).mVis=3D1 PPTSld.location.replace(MHTMLPrefix+href) } function SldUpdated( id ) { if( id =3D=3D GetHrefObj(gCurSld).mSldHref ) return gPrevSld=3DgCurSld gCurSld=3DGetSldNum(id) if( IsFramesMode() ) { UpdNavPane(); UpdOtlPane(); UpdNtsPane() } } function PrevSldViewed(){ GoToSld( GetHrefObj(gPrevSld).mSldHref ) } function HasPrevSld() { return ( gIsEndShow || ( gCurSld !=3D 1 && GetHrefO= bj( gCurSld-1 ).mVis =3D=3D 1 )||( GetCurSldNum() > 1 ) ) } function HasNextSld() { return (GetCurSldNum() !=3D GetNumSlds()) } function CloseWindow() { if( HideMenu() ) return; var event =3D PPTSld.event; if( !IsFramesMode() && event && (event.keyCode=3D=3D27 || event.keyCode=3D= =3D32 || event.type=3D=3D"click" ) ) window.close( self ); CatchNumKeys( self, event ); } function Unload() { gIsEndShow=3D0; } function SetupEndShow() { gIsEndShow=3D1; PPTSld.document.body.scroll=3D"no"; PPTSld.document.onkeypress=3DCloseWindow; PPTSld.document.onclick=3DCloseWindow; PPTSld.document.oncontextmenu=3D_CM; } function EndShow() { if( IsFramesMode() ) return if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue doc=3DPPTSld.document var dir =3D doc.body.dir if( dir !=3D "rtl" ) dir =3D "ltr"; doc.open() doc.writeln('


' + ENDSHOW_MESG + '

') doc.close() } function SetSldVisited(){ GetSldList().mList[gCurSld-1].mVisited=3Dtrue } function IsSldVisited(){ return GetSldList().mList[gCurSld-1].mVisited } function hrefList( sldHref, visible, advDelay, advClk ) { this.mSldHref=3D this.mNtsHref =3D sldHref this.mOrigVis=3D this.mVis =3D visible this.mVisited=3D false this.mAdvDelay=3D advDelay this.mAdvOnClk=3D advClk } function SldList(arr,curSld,fEnd) { this.mCurSld =3D curSld; this.mList =3D new Array(); var idx =3D 1; for(ii=3D0;ii 0) { PushSldList(sldList,fEnd); gCurSld =3D 1; } else if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue } function PushSldList(arr,fEnd) { var ii =3D gSldStack.length; gSldStack[ii] =3D new SldList(arr,gCurSld,fEnd); GoToSld( gSldStack[ii].mList[0].mSldHref ); } function PopSldList() { if (gSldStack[gSldStack.length-1].fEndShow) EndShow() else { gCurSld =3D gSldStack[gSldStack.length-1].mCurSld; gSldStack[gSldStack.length-1] =3D null; gSldStack.length--; var sldList =3D gSldStack[gSldStack.length-1]; GoToSld( sldList.mList[gCurSld - 1].mSldHref ); } } var custShowList=3Dnew Array(); function ImgBtn( oId,bId,w,action ) { var t=3Dthis t.Perform =3D _IBP t.SetActive =3D _IBSetA t.SetInactive=3D _IBSetI t.SetPressed =3D _IBSetP t.SetDisabled=3D _IBSetD t.Enabled =3D _IBSetE t.ChangeIcon =3D null t.UserAction =3D action t.ChgState =3D _IBUI t.mObjId =3D oId t.mBorderId=3D bId t.mWidth =3D w t.mIsOn =3D t.mCurState =3D 0 } function _IBSetA() { if( this.mIsOn ) { obj=3Dthis.ChgState( gHiliteClr,gShadowClr,2 ) obj.style.posTop=3D0 } } function _IBSetI() { if( this.mIsOn ) { obj=3Dthis.ChgState( gFaceClr,gFaceClr,1 ) obj.style.posTop=3D0 } } function _IBSetP() { if( this.mIsOn ) { obj=3Dthis.ChgState( gShadowClr,gHiliteClr,2 ) obj.style.posLeft+=3D1; obj.style.posTop+=3D1 } } function _IBSetD() { obj=3Dthis.ChgState( gFaceClr,gFaceClr,0 ) obj.style.posTop=3D0 } function _IBSetE( state ) { var t=3Dthis GetObj( t.mBorderId ).style.visibility=3D"visible" if( state !=3D t.mIsOn ) { t.mIsOn=3Dstate if( state ) t.SetInactive() else t.SetDisabled() } } function _IBP() { var t=3Dthis if( t.mIsOn ) { if( t.UserAction !=3D null ) t.UserAction() if( t.ChangeIcon ) { obj=3DGetObj(t.mObjId) if( t.ChangeIcon() ) obj.style.posLeft=3Dobj.style.posLeft+(t.mCurState-4)*t.mWidth else obj.style.posLeft=3Dobj.style.posLeft+(t.mCurState-0)*t.mWidth } t.SetActive() } } function _IBUI( clr1,clr2,nextState ) { var t=3Dthis SetBorder( GetObj( t.mBorderId ),clr1,clr2 ) obj=3DGetObj( t.mObjId ) obj.style.posLeft=3Dobj.style.posLeft+(t.mCurState-nextState)*t.mWidth-obj= .style.posTop t.mCurState=3DnextState return obj } function TxtBtn( oId,oeId,action,chkState ) { var t=3Dthis t.Perform =3D _TBP t.SetActive =3D _TBSetA t.SetInactive=3D _TBSetI t.SetPressed =3D _TBSetP t.SetDisabled=3D _TBSetD t.SetEnabled =3D _TBSetE t.GetState =3D chkState t.UserAction =3D action t.ChgState =3D _TBUI t.mObjId =3D oId t.m_elementsId=3D oeId t.mIsOn =3D 1 } function _TBSetA() { var t=3Dthis if( t.mIsOn && !t.GetState() ) t.ChgState( gHiliteClr,gShadowClr,0,0 ) } function _TBSetI() { var t=3Dthis if( t.mIsOn && !t.GetState() ) t.ChgState( gFaceClr,gFaceClr,0,0 ) } function _TBSetP() { if( this.mIsOn ) this.ChgState( gShadowClr,gHiliteClr,1,1 ) } function _TBSetD() { this.ChgState( gFaceClr,gFaceClr,0,0 ) this.mIsOn =3D 0 } function _TBSetE() { var t=3Dthis if( !t.GetState() ) t.ChgState( gFaceClr,gFaceClr,0,0 ) else t.ChgState( gShadowClr,gHiliteClr,1,1 ) t.mIsOn =3D 1 } function _TBP() { var t=3Dthis if( t.mIsOn ) { if( t.UserAction !=3D null ) t.UserAction() if( !t.GetState ) return if( t.GetState() ) t.SetPressed() else t.SetActive() } } function _TBUI( clr1,clr2,lOffset,tOffset ) { SetBorder( GetObj( this.mObjId ),clr1,clr2 ) Offset( GetObj( this.m_elementsId ),lOffset,tOffset ) } function Offset( obj, top, left ){ obj.style.top=3Dtop; obj.style.left=3Dle= ft } function SetBorder( obj, upperLeft, lowerRight ) { s=3Dobj.style; s.borderStyle =3D "solid" s.borderWidth =3D 1 s.borderLeftColor =3D s.borderTopColor =3D upperLeft s.borderBottomColor=3D s.borderRightColor =3D lowerRight } function GetBtnObj(){ return gBtnArr[window.event.srcElement.id] } function BtnOnOver(){ b=3DGetBtnObj(); if( b !=3D null ) b.SetActive() } function BtnOnDown(){ b=3DGetBtnObj(); if( b !=3D null ) b.SetPressed() } function BtnOnOut(){ b=3DGetBtnObj(); if( b !=3D null ) b.SetInactive() } function BtnOnUp() { b=3DGetBtnObj() if( b !=3D null ) b.Perform() else Upd() } function GetNtsState(){ return parent.gNtsOpen } function GetOtlState(){ return parent.gOtlOpen } function GetOtlTxtState(){ return parent.gOtlTxtExp } function NtsBtnSetFlag( fVal ) { s=3Ddocument.all.item( this.m_flagId ).style s.display=3D"none" if( fVal ) s.display=3D"" else s.display=3D"none" } function _BSetA_Border(){ b =3D gBtnArr[this.mObjId]; if( b !=3D null ) b.S= etActive() } function _BSetI_Border(){ b =3D gBtnArr[this.mObjId]; if( b !=3D null ) b.S= etInactive() } function _BSetP_Border(){ b =3D gBtnArr[this.mObjId]; if( b !=3D null ) b.S= etPressed() } function _BSetA_BorderImg() { b =3D gBtnArr[this.mBorderId] if( b !=3D null && this.mIsOn && !b.GetState() ) { obj=3Dthis.ChgState( gHiliteClr,gShadowClr,2 ) obj.style.posTop=3D0 } } function _BSetI_BorderImg() { b =3D gBtnArr[this.mBorderId] if( b !=3D null && this.mIsOn && !b.GetState() ) { obj=3Dthis.ChgState( gFaceClr,gFaceClr,1 ) obj.style.posTop=3D0 } } var gHiliteClr=3D"THREEDHIGHLIGHT",gShadowClr=3D"THREEDSHADOW",gFaceClr=3D"= THREEDFACE" var gBtnArr =3D new Array() gBtnArr["nb_otl"] =3D new TxtBtn( "nb_otl","nb_otlElem",parent.ToggleOtlPan= e,GetOtlState ) gBtnArr["nb_otlElem"] =3D new TxtBtn( "nb_otl","nb_otlElem",parent.ToggleOt= lPane,GetOtlState ) gBtnArr["nb_nts"] =3D new ImgBtn( "nb_nts","nb_ntsBorder",10,parent.ToggleN= tsPane ) gBtnArr["nb_nts"].SetActive =3D _BSetA_BorderImg; gBtnArr["nb_nts"].SetInactive =3D _BSetI_BorderImg; gBtnArr["nb_ntsBorder"] =3D new TxtBtn( "nb_ntsBorder","nb_ntsElem",parent.= ToggleNtsPane,GetNtsState ) gBtnArr["nb_ntsElem"] =3D new TxtBtn( "nb_ntsBorder","nb_ntsElem",parent.To= ggleNtsPane,GetNtsState ) gBtnArr["nb_prevBorder"] =3D gBtnArr["nb_prev"]=3D new ImgBtn( "nb_prev","n= b_prevBorder",30,parent.GoToPrevSld ) gBtnArr["nb_nextBorder"] =3D gBtnArr["nb_next"]=3D new ImgBtn( "nb_next","n= b_nextBorder",30,parent.GoToNextSld ) gBtnArr["nb_sldshw"]=3D new ImgBtn( "nb_sldshw","nb_sldshwBorder",18,parent= .FullScreen ) gBtnArr["nb_sldshwBorder"] =3D new TxtBtn( "nb_sldshw","nb_sldshwBorder",pa= rent.FullScreen,null ) gBtnArr["nb_sldshwBorder"].SetActive =3D _BSetA_Border; gBtnArr["nb_sldshwBorder"].SetInactive =3D _BSetI_Border; gBtnArr["nb_sldshwText"] =3D new TxtBtn( "nb_sldshw","nb_sldshwText",parent= .FullScreen,null ) gBtnArr["nb_sldshwText"].SetActive =3D _BSetA_Border; gBtnArr["nb_sldshwText"].SetInactive =3D _BSetI_Border; gBtnArr["nb_voice"] =3D gBtnArr["nb_voiceBorder"] =3D new ImgBtn( "nb_voice= ","nb_voiceBorder",18,parent.ToggleVNarration ) gBtnArr["nb_otlTxtBorder"] =3D gBtnArr["nb_otlTxt"]=3D new ImgBtn( "nb_otlT= xt","nb_otlTxtBorder",23,parent.ToggleOtlText ) gBtnArr["nb_ntsBorder"].m_flagId=3D "nb_nts" gBtnArr["nb_ntsBorder"].SetFlag =3D NtsBtnSetFlag gBtnArr["nb_otlTxt"].ChangeIcon=3D GetOtlTxtState var sNext=3D"Next",sPrev=3D"Previous",sEnd=3D"End Show",sFont=3D"Arial",sAr= row=3D"Arrow",sFreeform=3D"Freeform",sRect=3D"Rectangle",sOval=3D"Oval" function ShowMenu() { BuildMenu(); var doc=3DPPTSld.document.body,x=3DPPTSld.event.clientX+doc.scrollLeft,y= =3DPPTSld.event.clientY+doc.scrollTop m =3D PPTSld.document.all.item("ctxtmenu") m.style.pixelLeft=3Dx if( (x+m.scrollWidth > doc.clientWidth)&&(x-m.scrollWidth > 0) ) m.style.pixelLeft=3Dx-m.scrollWidth m.style.pixelTop=3Dy if( (y+m.scrollHeight > doc.clientHeight)&&(y-m.scrollHeight > 0) ) m.style.pixelTop=3Dy-m.scrollHeight m.style.display=3D"" } function _CM() { if( !parent.IsFullScrMode() ) return; if(!PPTSld.event.ctrlKey) { ShowMenu() return false } else HideMenu() } function BuildMenu() { if( PPTSld.document.all.item("ctxtmenu") ) return var mObj=3DCreateItem( PPTSld.document.body ) mObj.id=3D"ctxtmenu" mObj.style.visibility=3D"hidden" var s=3DmObj.style s.position=3D"absolute" s.cursor=3D"default" s.width=3D"120px" SetCMBorder(mObj,"menu","black") var iObj=3DCreateItem( mObj ) SetCMBorder( iObj, "threedhighlight","threedshadow" ) iObj.style.padding=3D2 CreateMenuItem( iObj,sNext,M_GoNextSld,M_True ) CreateMenuItem( iObj,sPrev,M_GoPrevSld,M_HasPrevSld ) CreateSeparator( iObj ) CreateMenuItem( iObj,sEnd,M_End,M_True ) mObj.style.visibility=3D"visible" } function Cancel() { window.event.cancelBubble=3Dtrue; window.event.returnVa= lue=3Dfalse } function Highlight() { ChangeClr("activecaption","threedhighlight") } function Deselect() { ChangeClr("threedface","menutext") } function Perform() { e=3DPPTSld.event.srcElement if( e.type=3D=3D"menuitem" && e.IsActive() ) e.Action() else PPTSld.event.cancelBubble=3Dtrue } function ChangeClr( bg,clr ) { e=3DPPTSld.event.srcElement if( e.type=3D=3D"menuitem" && e.IsActive() ) { e.style.backgroundColor=3Dbg e.style.color=3Dclr } } function M_HasPrevSld() { return( parent.HasPrevSld() ) } function M_GoNextSld() { if( gIsEndShow ) M_End(); 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charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition ------=_NextPart_01C91D68.307CCF60 Content-Location: file:///C:/A7293656/c1210L16_files/outline.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii"
 No= tes
Slide Show
Outline
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