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Lecture Notes
Alan D. Earhart
= Southeast Community College • Lincoln, NE
Chapter 1 <= /div>
Chemistry: Matter and Measurement
John E. McMurry • Robert C. Fay=
C
H
E
M
I
S
T
R
Y
Fif= th Edition
Click to edit Master title style
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Second level
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= Copyright © 2008 Pearson Prentice Hall, Inc.
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= Chapter 1: Chemistry: Matter and Measurement
= 10/1/2008
= Copyright © 2008 Pearson Prentice Hall, Inc.
= ‹#›
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Accur= acy, Precision, and Significant= Figures
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 1/1
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 1/2
Accuracy, Precision, and Significant Figures=
Accuracy: How close to t= he true value a given measurement is.
•Sing= le measurement: percent error
•Seri= es of measurements: average
•
P= recision: How well a number of independent measurements agree with each other. Characterized by the standard deviation.
A rela= tively low standard deviation means good precision while a relatively high standard deviation means poor precision.
Proper= equipment calibration can help ensure accuracy while the operator can help ensure precision (for one example).
Darts = are commonly used for one example. I also like to discuss bowling and how it relates.<= /font>
------=_NextPart_01C923A9.BCD06930 Content-Location: file:///C:/253949B3/c1210L3_files/slide0107.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 1/3
3D"slide0048_image094.jpg
Accuracy, Precision, and Significant Figures=
good accuracy
good precision
Mass of a Tennis Ball
The as= sumption is that the analytical balance is properly calibrated.
The da= ta only varies in the fourth decimal place.
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file:///C:/253949B3/c1210L3_files/slide0108.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 1/4
3D"slide0048_image094.jpg
Accuracy, Precision, and Significant Figures=
good accuracy
poor precision
Mass of a Tennis Ball
The da= ta varies in the first decimal place. While the accuracy is reasonable compared to the analytical balance, the precision is not.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 1/5
3D"slide0048_image094.jpg
Accuracy, Precision, and Significant Figures=
poor accuracy
poor precision
Mass of a Tennis Ball
The ba= throom scale is not something one would want to use for scientific measurements!
It is = possible to have good precision and poor accuracy. An instrument calibrated improperl= y, for example.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 1/6
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 1/7
Accuracy, Precision, and Significant Figures=
Significant figures: The number of meaningful digits in a measured or calculated quantity. They come from uncertainty in any measurement.
Gener= ally the last digit in a reported measurement is uncertain (estimated). = ;
Exact numbers and relationships (7 days in a week, 30 students in a clas= s, etc.) effectively have an infinite number of significant figu= res.
------=_NextPart_01C923A9.BCD06930 Content-Location: file:///C:/253949B3/c1210L3_files/slide0111.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 1/8
Accuracy, Precision, and Significant Figures=
length =3D 1.74 cm
0
1
2
4
3
cm
1.7 cm < length < 1.8 cm
Generally, estimate one place beyond markings!
Tells reader the accuracy of the equipment used for
 measurement
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 1/9
3D"01_P15.jpg"
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 1/10
Accuracy, Precision, and Significant Figures=
4.803 cm 4 SF
Rules for counting significant figures (left-to-right):
= 1.Zeros in the middle of a number are like any other digit; they are always significant.
------=_NextPart_01C923A9.BCD06930 Content-Location: file:///C:/253949B3/c1210L3_files/slide0113.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 1/11
Accuracy, Precision, and Significant Figures=
0.00661 g 3 SF (or 6.61 x= 10-3=  g)
Rules for counting significant figures (left-to-right):
= 1.Zeros in the middle of a number are like any other digit; they are always significant.
2.
2.Zeros at the beginning of a number are not significant (placeholders= ).
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 1/12
Accuracy, Precision, and Significant Figures=
55.220 K 5 SF
Rules for counting significant figures (left-to-right):
= 1.Zeros in the middle of a number are like any other digit; they are always significant.
2.
2.Zeros at the beginning of a number are not significant (placeholders).
3.
= 3.Zeros at the end of a number and after the decimal point are always significant.
------=_NextPart_01C923A9.BCD06930 Content-Location: file:///C:/253949B3/c1210L3_files/slide0115.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 1/13
Accuracy, Precision, and Significant Figures=
Rules for counting significant figures (left-to-right):
= 1.Zeros in the middle of a number are like any other digit; they are always significant.
2.
2.Zeros at the beginning of a number are not significant (placeholders).
3.
= 3.Zeros at the end of a number and after the decimal point are always significant.
4.
4.Zeros at the end of a number and before the decimal point may or may = not be significant.
34,200 m ? SF
Use sc= ientific notation in these cases when reporting the results of calculations.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 1/14
Rounding Numbers
Math rules for keeping track of significant figures:
•Multiplication or division: The answer canR= 17;t have more significant figures than any of the original numbers.
11.70 gal
278 mi
=3D 23.8 mi/gal
4 SF
3 SF
3 SF
These = rules are approximations that work well. A proper analysis would be a more detailed look at error analysis and is often done in a first quarter physical chemistry class for chemistry majors (or something similar).
------=_NextPart_01C923A9.BCD06930 Content-Location: file:///C:/253949B3/c1210L3_files/slide0116_image013.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhVgA7AHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAIAGQBR AAMAgAAAAAAAAAIZRIynyesNn4x0houz3rz7D4aXIZbmiWZAAQA7 ------=_NextPart_01C923A9.BCD06930 Content-Location: file:///C:/253949B3/c1210L3_files/slide0116_image014.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhNQALAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAMAAgAx AAkAgAAAAAAAAAIohI+py80RnJwSWoozsLxHDSZXRHrQhpLhclabaa6fnL6xOq90rPdLAQA7 ------=_NextPart_01C923A9.BCD06930 Content-Location: file:///C:/253949B3/c1210L3_files/slide0116_image015.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhLAALAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAMAAAAo AAgAgAAAAAAAAAIkhI+pyxYN25uh2opePPR6aHFA503juY1lmaaf2cYcJteJZrcFADs= ------=_NextPart_01C923A9.BCD06930 Content-Location: file:///C:/253949B3/c1210L3_files/slide0116_image016.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhCgArAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAIAAQAH ACgAgAAAAAAAAAIoBBKmt5b9FGoM0uiwu3xNC3qQVolh1pkqem7tt7oxLEnIneG5p9FyAQA7 ------=_NextPart_01C923A9.BCD06930 Content-Location: file:///C:/253949B3/c1210L3_files/slide0117.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 1/15
Rounding Numbers
Math rules for keeping track of significant figures:
•Multiplication or division: The answer canR= 17;t have more significant figures than any of the original numbers.
•
•Addition or subtraction: The answer can’t have more digits to the right of the decimal point than any of the original numbers.
3.19
+ 0.01315
3.18
2 decimal places
5 decimal places
2 decimal places
------=_NextPart_01C923A9.BCD06930 Content-Location: file:///C:/253949B3/c1210L3_files/slide0117_image017.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhWAADAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAEAAABW AAMAgAAAAAAAAAIaRIynyesNn4x0yoCz3rz7D4biBlSmdaboWhUAOx== ------=_NextPart_01C923A9.BCD06930 Content-Location: file:///C:/253949B3/c1210L3_files/slide0117_image018.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhUABcAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAEAAQBM AFkAgAAAAAAAAALDhI+py+0Po5zUhVuzzrfjDYaI94kmFQCkd7bPmhqlS6sqW+cKqfdHyvP1gsIc EFesEZOuY4epXEFbztlUtLyGqjEtFukFccPfJ7l5TqvX7Lb7DY/L5/S6/Y7P6/f8vv8PGCjI0eUD ZHOYiLio2HhjZgQjOUlJGQh5WTi4ydnp+QkaKjpKWmp6ipqqusra6voKGytLk+XHhaFpKzk4dgh4 6/uXyBKsC2Pz+0jMuyvYiyysjJlgNTf81JWbV5lZuzdtq1AAADs= ------=_NextPart_01C923A9.BCD06930 Content-Location: file:///C:/253949B3/c1210L3_files/slide0118.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 1/16
Rounding Numbers
Rules for rounding off numbers:
1.If the first digit you remove is less than 5, round down by dropping it and all following numbers.
5.664 525 =3D = 5.66
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 1/17
Rounding Numbers
Rules for rounding off numbers:
1.If the first digit you remove is less than 5, round down by dropping it and all following numbers.
2.
2.If the first digit you remove is 6 or greater, round up by adding 1 to the digit on the left.
5.664 525 =3D = 5.7
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 1/18
Rounding Numbers
Rules for rounding off numbers:
1.If the first digit you remove is less than 5, round down by dropping it and all following numbers.
2.
2.If the first digit you remove is 6 or greater, round up by adding 1 to the digit on the left.
3.
3.If the first digit you remove is 5 and there are more nonzero digits following, round up.
5.664 525 =3D = 5.665
Books = sometimes use different rules for this one.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 1/19
Rounding Numbers
Rules for rounding off numbers:
1.If the first digit you remove is less than 5, round down by dropping it and all following numbers.
2.
2.If the first digit you remove is 6 or greater, round up by adding 1 to the digit on the left.
3.
3.If the first digit you remove is 5 and there are more nonzero digits following, round up.
4.
4.If the digit you remove is a 5 with nothing following, round down.
5.664 525 =3D 5.664 52
If the= re were zeros following that last 5, the rule is the same.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 1/20
Rounding Numbers
Rules for rounding off numbers:
1.To minimize rounding errors, carry extra digits, and round only at the end of the calculation.
2.
If the= re were zeros following that last 5, the rule is the same.
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H4 – C1
•1.25*, 1.27, 1.55, 1= .58, 1.60, 1.62, 1.63*, 1.70, 1.71*, 1.105*
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= Chapter 1: Chemistry: Matter and Measurement
= 10/1/2008
Click to edit Master text styles
Second level
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= Copyright © 2008 Pearson Prentice Hall, Inc.
= ‹#›
Chapter 1: Chemistry: Matter and Measurement
10/1/2008
Copyright © 2008 Pearson Prentice Hall, Inc.
2
A relative= ly low standard deviation means good precision while a relatively high standard d= eviation means poor precision.
Proper equ= ipment calibration can help ensure accuracy while the operator can help ensure pr= ecision (for one example).
Darts are = commonly used for one example. I also like to discuss bowling and how it relates.
Chapter 1: Chemistry: Matter and Measurement
10/1/2008
Copyright © 2008 Pearson Prentice Hall, Inc.
3
The assump= tion is that the analytical balance is properly calibrated.
The data o= nly varies in the fourth decimal place.
Chapter 1: Chemistry: Matter and Measurement
10/1/2008
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4
The data varies in the= first decimal place. While the accuracy is reasonable compared to the analytical balance, the precision is not.
Chapter 1: Chemistry: Matter and Measurement
10/1/2008
Copyright © 2008 Pearson Prentice Hall, Inc.
5
The bathro= om scale is not something one would want to use for scientific measurements!
It is poss= ible to have good precision and poor accuracy. An instrument calibrated improperly, for example.
Chapter 1: Chemistry: Matter and Measurement
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Copyright © 2008 Pearson Prentice Hall, Inc.
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Chapter 1: Chemistry: Matter and Measurement
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Chapter 1: Chemistry: Matter and Measurement
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Chapter 1: Chemistry: Matter and Measurement
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Chapter 1: Chemistry: Matter and Measurement
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Chapter 1: Chemistry: Matter and Measurement
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13
Use scient= ific notation in these cases when reporting the results of calculations.
Chapter 1: Chemistry: Matter and Measurement
10/1/2008
Copyright © 2008 Pearson Prentice Hall, Inc.
14
These rule= s are approximations that work well. A proper analysis would be a more detailed = look at error analysis and is often done in a first quarter physical chemistry class for chemistry majors (or something similar).
Chapter 1: Chemistry: Matter and Measurement
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15
Chapter 1: Chemistry: Matter and Measurement
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Chapter 1: Chemistry: Matter and Measurement
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17
Chapter 1: Chemistry: Matter and Measurement
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18
Books some= times use different rules for this one.
Chapter 1: Chemistry: Matter and Measurement
10/1/2008
Copyright © 2008 Pearson Prentice Hall, Inc.
19
If there w= ere zeros following that last 5, the rule is the same.
Chapter 1: Chemistry: Matter and Measurement
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20
If there w= ere zeros following that last 5, the rule is the same.
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&& parent.IsFramesMode() ) padding=3D6 cltWidth=3Ddocument.body.clientWidth-padding cltHeight=3Ddocument.body.clientHeight-padding factor=3D(1.0*cltWidth)/g_origW if( cltHeight < g_origH*factor ) factor=3D(1.0*cltHeight)/g_origH newSize =3D g_origSz * factor if( newSize < 1 ) newSize=3D1 s=3DSlideObj.style s.fontSize=3DnewSize+"px" s.posWidth=3Dg_origW*factor s.posHeight=3Dg_origH*factor s.posLeft=3D(cltWidth-s.posWidth+padding)/2 s.posTop=3D(cltHeight-s.posHeight+padding)/2 if( g_scaleHyperlinks ) ScaleHyperlinks( factor ) } function _InitAnimations() { animRuntimeInstalled =3D ''+document.body.localTime !=3D 'undefined'; isFullScreen =3D (window.name =3D=3D "PPTSld") && !parent.IsFramesMode(); g_animUseRuntime =3D g_showAnimation && animRuntimeInstalled && !(isFullSc= reen && parent.IsSldVisited()); if( g_animUseRuntime ) { collSeq =3D document.all.tags("seq"); if( collSeq !=3D null ) { for(ii=3D0;ii numSlds ) gSldJumpIdx =3D numSlds; if ( gSldJumpIdx >=3D 0 ) { if ( gSldJumpIdx =3D=3D 0 ) gSldJumpIdx =3D 1; var jumpTo =3D parseInt(gSldJumpIdx); gSldJump =3D 0; gSldJumpIdx =3D ""; win.GoToSld( parent.GetSldList().mList[jumpTo-1].mSldHref ) } } } function _KDH() { if( event.keyCode =3D=3D 8 ) { event.returnValue =3D 0; parent.GoToPrevSld(); } } function DocumentOnClick() { if( IsNts() || parent.HideMenu() ) return; if( ( g_allowAdvOnClick && (window.name=3D=3D"PPTSld") && !parent.IsFrames= Mode() ) || (event && event.keyCode=3D=3D32) ) { if( g_animUseRuntime && g_animMainSequence && g_animMainSequence.cangonex= t ) return; parent.GoToNextSld(); } } var g_supportsPPTHTML =3D SupportsPPTHTML(), g_scaleInFrame =3D 1, gId=3D""= , g_bgSound=3D"", g_scaleHyperlinks =3D false, g_allowAdvOnClick =3D 1, g_showInBrowser = =3D 0, gLoopCont =3D 0, gUseSldTimings =3D 1; var g_showAnimation =3D g_supportsPPTHTML && SupportsPPTAnimation() && ( (w= indow.name=3D=3D"PPTSld" && !parent.IsFramesMode()) || g_showInBrowser );va= r g_animManager =3D null; var g_animUseRuntime =3D false; var g_animItemsToHide, g_animInteractiveItems, g_animSlideTime; var g_animMainSequence =3D null; var ENDSHOW_MESG=3D"End of slide show, click to exit.", SCREEN_MODE=3D"Fram= es", gIsEndShow=3D0, NUM_VIS_SLDS=3D21, SCRIPT_HREF=3D"script.js", FULLSCR_= HREF=3D"fullscreen.htm"; var gCurSld =3D gPrevSld =3D 1, g_offset =3D 0, gNtsOpen =3D gHasNts =3D gO= tlTxtExp =3D 0, gHasNarration =3D 0, gOtlOpen =3D true window.gPPTHTML=3DSupportsPPTHTML() var gMainDoc=3Dnew Array(new hrefList("slide0105.htm",1,-1,1),new hrefList(= "slide0106.htm",1,-1,1),new hrefList("slide0107.htm",1,-1,1),new hrefList("= slide0108.htm",1,-1,1),new hrefList("slide0109.htm",1,-1,1),new hrefList("s= lide0122.htm",1,-1,1),new hrefList("slide0110.htm",1,-1,1),new hrefList("sl= ide0111.htm",1,-1,1),new hrefList("slide0124.htm",1,-1,1),new hrefList("sli= de0112.htm",1,-1,1),new hrefList("slide0113.htm",1,-1,1),new hrefList("slid= e0114.htm",1,-1,1),new hrefList("slide0115.htm",1,-1,1),new hrefList("slide= 0116.htm",1,-1,1),new hrefList("slide0117.htm",1,-1,1),new hrefList("slide0= 118.htm",1,-1,1),new hrefList("slide0119.htm",1,-1,1),new hrefList("slide01= 20.htm",1,-1,1),new hrefList("slide0121.htm",1,-1,1),new hrefList("slide012= 3.htm",1,-1,1),new hrefList("slide0104.htm",1,-1,1)); function FullScrInit() { g_allowAdvOnClick =3D GetCurSld().mAdvOnClk document.body.style.backgroundColor=3D"black" document.oncontextmenu=3Dparent._CM; document.onkeydown =3D _KDH; document.ondragstart=3DCancel document.onselectstart=3DCancel self.focus() } function Redirect( frmId ) { var str=3Ddocument.location.hash,idx=3Dstr.indexOf('#'), sId=3DGetSldId() if(idx>=3D0) str=3Dstr.substr(1); if( window.name !=3D frmId && ( sId !=3D str) ) { obj =3D GetObj("Main-File") window.location.href=3Dobj.href+"#"+sId return 1 } return 0 } var MHTMLPrefix =3D CalculateMHTMLPrefix(); function CalculateMHTMLPrefix() { if ( document.location.protocol =3D=3D 'mhtml:') { href=3Dnew String(document.location.href) Start=3Dhref.indexOf('!')+1 End=3Dhref.lastIndexOf('/')+1 if (End < Start) return href.substring(0, Start) else return href.substring(0, End) } return ''; } function GetTags(base,tag) { if(g_supportsPPTHTML) return base.all.tags(tag); else return base.getElementsByTagName(tag); } function UpdNtsPane(){ if(frames["PPTNts"]) PPTNts.location.replace( MHTMLP= refix+GetHrefObj( gCurSld ).mNtsHref ) } function UpdNavPane( sldIndex ){ if(gNavLoaded) PPTNav.UpdNav() } function UpdOtNavPane(){ if(gOtlNavLoaded) PPTOtlNav.UpdOtlNav() } function UpdOtlPane(){ if(gOtlLoaded) PPTOtl.UpdOtl() } function SetHasNts( fVal ) { if( gHasNts !=3D fVal ) { gHasNts=3DfVal UpdNavPane() } } function ToggleOtlText() { gOtlTxtExp=3D!gOtlTxtExp UpdOtlPane() } function ClearMedia() { if (PPTSld.pptSound) PPTSld.pptSound.loop =3D 0; } function FullScreen() { if ( PPTSld.g_animUseRuntime ) PPTSld.document.body.pause(); ClearMedia(); var href =3D ( document.location.protocol =3D=3D 'mhtml:') ? FULLSCR_HREF = : FULLSCR_HREF+"#"+GetHrefObj(gCurSld).mSldHref; if(PPTNav.event.ctrlKey) { var w =3D (window.screen.availWidth * 1.0) / 2.0 var h =3D w * (PPTSld.g_origH * 1.0) / PPTSld.g_origW win =3D window.open( MHTMLPrefix+href,null,"toolbar=3D0,resizable=3D1,top= =3D0,left=3D0," + "width=3D"+ w + ",height=3D" + h ); if( win.document.body && PPTSld.g_animUseRuntime ) win.document.body.PPTSldFrameset=3Dwindow; } else { win =3D window.open( MHTMLPrefix+href,null,"fullscreen=3Dyes" ); if( win.document.body && PPTSld.g_animUseRuntime ) win.document.body.PPTSldFrameset=3Dwindow; } } function ToggleVNarration() { rObj=3DPPTSld.document.all("NSPlay") if( rObj && !PPTSld.g_animUseRuntime ) { if( (rObj.playState =3D=3D 1)||(rObj.playState =3D=3D 0) ) rObj.Play() else if( rObj.playState =3D=3D 2 ) rObj.Pause() else return; } else if( PPTSld.g_animUseRuntime ) { narObj =3D PPTSld.document.all("narrationID") if( narObj ) narObj.togglePause() } } function GetCurSldNum() { obj=3DGetHrefObj(gCurSld) if( obj.mOrigVis =3D=3D 1 ) return obj.mSldIdx else return gCurSld } function GetNumSlds() { if( GetHrefObj(gCurSld).mOrigVis =3D=3D 1 ) return GetSldList().mNumVisSlds; else return GetSldList().mList.length } function GetSldNum( href ) { for(ii=3D0; ii 1 ) PopSldList(); else if( !IsFramesMode() ) { if( gLoopCont ) GoToFirst() else EndShow() } } function GoToPrevSld() { ii=3DgCurSld-1 if( ii > 0 ) { obj=3DGetHrefObj(ii) while ( obj && ( obj.mVis =3D=3D 0 ) && ( ii>0 ) ) obj=3DGetHrefObj(--ii) if( ii =3D=3D 0 ) ii=3D1 GoToSldNum(ii) } } function GoToFirst(){ GoToSld( GetHrefObj(1).mSldHref ) } function GoToLast() { ii=3DGetSldList().mList.length if( ii !=3D gCurSld ) GoToSld( GetHrefObj(ii).mSldHref ) } function GoToSldNum( num ) { if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue obj =3D GetHrefObj( num ) obj.mVis=3D1 gPrevSld=3DgCurSld gCurSld =3D num; PPTSld.location.replace(MHTMLPrefix+obj.mSldHref) if( IsFramesMode() ) { UpdNavPane(); UpdOtlPane(); UpdNtsPane() } } function GoToSld( href ) { if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue GetHrefObj( GetSldNum(href) ).mVis=3D1 PPTSld.location.replace(MHTMLPrefix+href) } function SldUpdated( id ) { if( id =3D=3D GetHrefObj(gCurSld).mSldHref ) return gPrevSld=3DgCurSld gCurSld=3DGetSldNum(id) if( IsFramesMode() ) { UpdNavPane(); UpdOtlPane(); UpdNtsPane() } } function PrevSldViewed(){ GoToSld( GetHrefObj(gPrevSld).mSldHref ) } function HasPrevSld() { return ( gIsEndShow || ( gCurSld !=3D 1 && GetHrefO= bj( gCurSld-1 ).mVis =3D=3D 1 )||( GetCurSldNum() > 1 ) ) } function HasNextSld() { return (GetCurSldNum() !=3D GetNumSlds()) } function CloseWindow() { if( HideMenu() ) return; var event =3D PPTSld.event; if( !IsFramesMode() && event && (event.keyCode=3D=3D27 || event.keyCode=3D= =3D32 || event.type=3D=3D"click" ) ) window.close( self ); CatchNumKeys( self, event ); } function Unload() { gIsEndShow=3D0; } function SetupEndShow() { gIsEndShow=3D1; PPTSld.document.body.scroll=3D"no"; PPTSld.document.onkeypress=3DCloseWindow; PPTSld.document.onclick=3DCloseWindow; PPTSld.document.oncontextmenu=3D_CM; } function EndShow() { if( IsFramesMode() ) return if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue doc=3DPPTSld.document var dir =3D doc.body.dir if( dir !=3D "rtl" ) dir =3D "ltr"; doc.open() doc.writeln('


' + ENDSHOW_MESG + '

') doc.close() } function SetSldVisited(){ GetSldList().mList[gCurSld-1].mVisited=3Dtrue } function IsSldVisited(){ return GetSldList().mList[gCurSld-1].mVisited } function hrefList( sldHref, visible, advDelay, advClk ) { this.mSldHref=3D this.mNtsHref =3D sldHref this.mOrigVis=3D this.mVis =3D visible this.mVisited=3D false this.mAdvDelay=3D advDelay this.mAdvOnClk=3D advClk } function SldList(arr,curSld,fEnd) { this.mCurSld =3D curSld; this.mList =3D new Array(); var idx =3D 1; for(ii=3D0;ii 0) { PushSldList(sldList,fEnd); gCurSld =3D 1; } else if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue } function PushSldList(arr,fEnd) { var ii =3D gSldStack.length; gSldStack[ii] =3D new SldList(arr,gCurSld,fEnd); GoToSld( gSldStack[ii].mList[0].mSldHref ); } function PopSldList() { if (gSldStack[gSldStack.length-1].fEndShow) EndShow() else { gCurSld =3D gSldStack[gSldStack.length-1].mCurSld; gSldStack[gSldStack.length-1] =3D null; gSldStack.length--; var sldList =3D gSldStack[gSldStack.length-1]; GoToSld( sldList.mList[gCurSld - 1].mSldHref ); } } var custShowList=3Dnew Array(); function ImgBtn( oId,bId,w,action ) { var t=3Dthis t.Perform =3D _IBP t.SetActive =3D _IBSetA t.SetInactive=3D _IBSetI t.SetPressed =3D _IBSetP t.SetDisabled=3D _IBSetD t.Enabled =3D _IBSetE t.ChangeIcon =3D null t.UserAction =3D action t.ChgState =3D _IBUI t.mObjId =3D oId t.mBorderId=3D bId t.mWidth =3D w t.mIsOn =3D t.mCurState =3D 0 } function _IBSetA() { if( this.mIsOn ) { obj=3Dthis.ChgState( gHiliteClr,gShadowClr,2 ) obj.style.posTop=3D0 } } function _IBSetI() { if( this.mIsOn ) { obj=3Dthis.ChgState( gFaceClr,gFaceClr,1 ) obj.style.posTop=3D0 } } function _IBSetP() { if( this.mIsOn ) { obj=3Dthis.ChgState( gShadowClr,gHiliteClr,2 ) obj.style.posLeft+=3D1; obj.style.posTop+=3D1 } } function _IBSetD() { obj=3Dthis.ChgState( gFaceClr,gFaceClr,0 ) obj.style.posTop=3D0 } function _IBSetE( state ) { var t=3Dthis GetObj( t.mBorderId ).style.visibility=3D"visible" if( state !=3D t.mIsOn ) { t.mIsOn=3Dstate if( state ) t.SetInactive() else t.SetDisabled() } } function _IBP() { var t=3Dthis if( t.mIsOn ) { if( t.UserAction !=3D null ) t.UserAction() if( t.ChangeIcon ) { obj=3DGetObj(t.mObjId) if( t.ChangeIcon() ) obj.style.posLeft=3Dobj.style.posLeft+(t.mCurState-4)*t.mWidth else obj.style.posLeft=3Dobj.style.posLeft+(t.mCurState-0)*t.mWidth } t.SetActive() } } function _IBUI( clr1,clr2,nextState ) { var t=3Dthis SetBorder( GetObj( t.mBorderId ),clr1,clr2 ) obj=3DGetObj( t.mObjId ) obj.style.posLeft=3Dobj.style.posLeft+(t.mCurState-nextState)*t.mWidth-obj= .style.posTop t.mCurState=3DnextState return obj } function TxtBtn( oId,oeId,action,chkState ) { var t=3Dthis t.Perform =3D _TBP t.SetActive =3D _TBSetA t.SetInactive=3D _TBSetI t.SetPressed =3D _TBSetP t.SetDisabled=3D _TBSetD t.SetEnabled =3D _TBSetE t.GetState =3D chkState t.UserAction =3D action t.ChgState =3D _TBUI t.mObjId =3D oId t.m_elementsId=3D oeId t.mIsOn =3D 1 } function _TBSetA() { var t=3Dthis if( t.mIsOn && !t.GetState() ) t.ChgState( gHiliteClr,gShadowClr,0,0 ) } function _TBSetI() { var t=3Dthis if( t.mIsOn && !t.GetState() ) t.ChgState( gFaceClr,gFaceClr,0,0 ) } function _TBSetP() { if( this.mIsOn ) this.ChgState( gShadowClr,gHiliteClr,1,1 ) } function _TBSetD() { this.ChgState( gFaceClr,gFaceClr,0,0 ) this.mIsOn =3D 0 } function _TBSetE() { var t=3Dthis if( !t.GetState() ) t.ChgState( gFaceClr,gFaceClr,0,0 ) else t.ChgState( gShadowClr,gHiliteClr,1,1 ) t.mIsOn =3D 1 } function _TBP() { var t=3Dthis if( t.mIsOn ) { if( t.UserAction !=3D null ) t.UserAction() if( !t.GetState ) return if( t.GetState() ) t.SetPressed() else t.SetActive() } } function _TBUI( clr1,clr2,lOffset,tOffset ) { SetBorder( GetObj( this.mObjId ),clr1,clr2 ) Offset( GetObj( this.m_elementsId ),lOffset,tOffset ) } function Offset( obj, top, left ){ obj.style.top=3Dtop; obj.style.left=3Dle= ft } function SetBorder( obj, upperLeft, lowerRight ) { s=3Dobj.style; s.borderStyle =3D "solid" s.borderWidth =3D 1 s.borderLeftColor =3D s.borderTopColor =3D upperLeft s.borderBottomColor=3D s.borderRightColor =3D lowerRight } function GetBtnObj(){ return gBtnArr[window.event.srcElement.id] } function BtnOnOver(){ b=3DGetBtnObj(); if( b !=3D null ) b.SetActive() } function BtnOnDown(){ b=3DGetBtnObj(); if( b !=3D null ) b.SetPressed() } function BtnOnOut(){ b=3DGetBtnObj(); if( b !=3D null ) b.SetInactive() } function BtnOnUp() { b=3DGetBtnObj() if( b !=3D null ) b.Perform() else Upd() } function GetNtsState(){ return parent.gNtsOpen } function GetOtlState(){ return parent.gOtlOpen } function GetOtlTxtState(){ return parent.gOtlTxtExp } function NtsBtnSetFlag( fVal ) { s=3Ddocument.all.item( this.m_flagId ).style s.display=3D"none" if( fVal ) s.display=3D"" else s.display=3D"none" } function _BSetA_Border(){ b =3D gBtnArr[this.mObjId]; if( b !=3D null ) b.S= etActive() } function _BSetI_Border(){ b =3D gBtnArr[this.mObjId]; if( b !=3D null ) b.S= etInactive() } function _BSetP_Border(){ b =3D gBtnArr[this.mObjId]; if( b !=3D null ) b.S= etPressed() } function _BSetA_BorderImg() { b =3D gBtnArr[this.mBorderId] if( b !=3D null && this.mIsOn && !b.GetState() ) { obj=3Dthis.ChgState( gHiliteClr,gShadowClr,2 ) obj.style.posTop=3D0 } } function _BSetI_BorderImg() { b =3D gBtnArr[this.mBorderId] if( b !=3D null && this.mIsOn && !b.GetState() ) { obj=3Dthis.ChgState( gFaceClr,gFaceClr,1 ) obj.style.posTop=3D0 } } var gHiliteClr=3D"THREEDHIGHLIGHT",gShadowClr=3D"THREEDSHADOW",gFaceClr=3D"= THREEDFACE" var gBtnArr =3D new Array() gBtnArr["nb_otl"] =3D new TxtBtn( "nb_otl","nb_otlElem",parent.ToggleOtlPan= e,GetOtlState ) gBtnArr["nb_otlElem"] =3D new TxtBtn( "nb_otl","nb_otlElem",parent.ToggleOt= lPane,GetOtlState ) gBtnArr["nb_nts"] =3D new ImgBtn( "nb_nts","nb_ntsBorder",10,parent.ToggleN= tsPane ) gBtnArr["nb_nts"].SetActive =3D _BSetA_BorderImg; gBtnArr["nb_nts"].SetInactive =3D _BSetI_BorderImg; gBtnArr["nb_ntsBorder"] =3D new TxtBtn( "nb_ntsBorder","nb_ntsElem",parent.= ToggleNtsPane,GetNtsState ) gBtnArr["nb_ntsElem"] =3D new TxtBtn( "nb_ntsBorder","nb_ntsElem",parent.To= ggleNtsPane,GetNtsState ) gBtnArr["nb_prevBorder"] =3D gBtnArr["nb_prev"]=3D new ImgBtn( "nb_prev","n= b_prevBorder",30,parent.GoToPrevSld ) gBtnArr["nb_nextBorder"] =3D gBtnArr["nb_next"]=3D new ImgBtn( "nb_next","n= b_nextBorder",30,parent.GoToNextSld ) gBtnArr["nb_sldshw"]=3D new ImgBtn( "nb_sldshw","nb_sldshwBorder",18,parent= .FullScreen ) gBtnArr["nb_sldshwBorder"] =3D new TxtBtn( "nb_sldshw","nb_sldshwBorder",pa= rent.FullScreen,null ) gBtnArr["nb_sldshwBorder"].SetActive =3D _BSetA_Border; gBtnArr["nb_sldshwBorder"].SetInactive =3D _BSetI_Border; gBtnArr["nb_sldshwText"] =3D new TxtBtn( "nb_sldshw","nb_sldshwText",parent= .FullScreen,null ) gBtnArr["nb_sldshwText"].SetActive =3D _BSetA_Border; gBtnArr["nb_sldshwText"].SetInactive =3D _BSetI_Border; gBtnArr["nb_voice"] =3D gBtnArr["nb_voiceBorder"] =3D new ImgBtn( "nb_voice= ","nb_voiceBorder",18,parent.ToggleVNarration ) gBtnArr["nb_otlTxtBorder"] =3D gBtnArr["nb_otlTxt"]=3D new ImgBtn( "nb_otlT= xt","nb_otlTxtBorder",23,parent.ToggleOtlText ) gBtnArr["nb_ntsBorder"].m_flagId=3D "nb_nts" gBtnArr["nb_ntsBorder"].SetFlag =3D NtsBtnSetFlag gBtnArr["nb_otlTxt"].ChangeIcon=3D GetOtlTxtState var sNext=3D"Next",sPrev=3D"Previous",sEnd=3D"End Show",sFont=3D"Arial",sAr= row=3D"Arrow",sFreeform=3D"Freeform",sRect=3D"Rectangle",sOval=3D"Oval" function ShowMenu() { BuildMenu(); var doc=3DPPTSld.document.body,x=3DPPTSld.event.clientX+doc.scrollLeft,y= =3DPPTSld.event.clientY+doc.scrollTop m =3D PPTSld.document.all.item("ctxtmenu") m.style.pixelLeft=3Dx if( (x+m.scrollWidth > doc.clientWidth)&&(x-m.scrollWidth > 0) ) m.style.pixelLeft=3Dx-m.scrollWidth m.style.pixelTop=3Dy if( (y+m.scrollHeight > doc.clientHeight)&&(y-m.scrollHeight > 0) ) m.style.pixelTop=3Dy-m.scrollHeight m.style.display=3D"" } function _CM() { if( !parent.IsFullScrMode() ) return; if(!PPTSld.event.ctrlKey) { ShowMenu() return false } else HideMenu() } function BuildMenu() { if( PPTSld.document.all.item("ctxtmenu") ) return var mObj=3DCreateItem( PPTSld.document.body ) mObj.id=3D"ctxtmenu" mObj.style.visibility=3D"hidden" var s=3DmObj.style s.position=3D"absolute" s.cursor=3D"default" s.width=3D"120px" SetCMBorder(mObj,"menu","black") var iObj=3DCreateItem( mObj ) SetCMBorder( iObj, "threedhighlight","threedshadow" ) iObj.style.padding=3D2 CreateMenuItem( iObj,sNext,M_GoNextSld,M_True ) CreateMenuItem( iObj,sPrev,M_GoPrevSld,M_HasPrevSld ) CreateSeparator( iObj ) CreateMenuItem( iObj,sEnd,M_End,M_True ) mObj.style.visibility=3D"visible" } function Cancel() { window.event.cancelBubble=3Dtrue; window.event.returnVa= lue=3Dfalse } function Highlight() { ChangeClr("activecaption","threedhighlight") } function Deselect() { ChangeClr("threedface","menutext") } function Perform() { e=3DPPTSld.event.srcElement if( e.type=3D=3D"menuitem" && e.IsActive() ) e.Action() else PPTSld.event.cancelBubble=3Dtrue } function ChangeClr( bg,clr ) { e=3DPPTSld.event.srcElement if( e.type=3D=3D"menuitem" && e.IsActive() ) { e.style.backgroundColor=3Dbg e.style.color=3Dclr } } function M_HasPrevSld() { return( parent.HasPrevSld() ) } function M_GoNextSld() { if( gIsEndShow ) M_End(); else GoToNextSld() } function M_GoPrevSld() { if( gIsEndShow ) { gIsEndShow=3D0; history.back();= PPTSld.event.cancelBubble=3Dtrue; } else GoToPrevSld() } function M_True() { return true } function M_End() { window.close( self ) } function CreateMenuItem( node,text,action,eval ) { var e=3DCreateItem( node ) e.type=3D"menuitem" e.Action=3Daction e.IsActive=3Deval e.innerHTML=3Dtext if( !e.IsActive() ) e.style.color=3D"threedshadow" e.onclick=3DPerform e.onmouseover=3DHighlight e.onmouseout=3DDeselect s=3De.style; s.fontFamily=3DsFont s.fontSize=3D"9pt" s.paddingLeft=3D2 } function CreateSeparator( node ) { var sObj=3DCreateItem( node ) SetCMBorder(sObj,"menu","menu") var s=3DsObj.style s.borderTopColor=3D"threedshadow" s.borderBottomColor=3D"threedhighlight" s.height=3D1 s.fontSize=3D"0px" } function CreateItem( node ) { var elem=3DPPTSld.document.createElement("DIV") node.insertBefore( elem ) return elem } function SetCMBorder( o,ltClr,rbClr ) { var s=3Do.style s.backgroundColor=3D"menu" s.borderStyle=3D"solid" s.borderWidth=3D1 s.borderColor=3DltClr+" "+rbClr+" "+rbClr+" "+ltClr } ------=_NextPart_01C923A9.BCD06930 Content-Location: file:///C:/253949B3/c1210L3_files/fullscreen.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; 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charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition ------=_NextPart_01C923A9.BCD06930 Content-Location: file:///C:/253949B3/c1210L3_files/outline.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii"
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Outline
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